SYNTHESIS AND CHARACTERIZATION OF THE FUL LERENE CO-CRYSTALS C-60-CENTER-DOT-12C(6)H(12), C-70-CENTER-DOT-12C(6)H(12), C-60-CENTER-DOT-12CCL(4), C-60-CENTER-DOT-2CHBR(3), C-60-CENTER-DOT-2CHCL(3), C-60-CENTER-DOT-2H(2)CCL(2)

Authors
JANSEN M WAIDMANN G
Citation
M. Jansen et G. Waidmann, SYNTHESIS AND CHARACTERIZATION OF THE FUL LERENE CO-CRYSTALS C-60-CENTER-DOT-12C(6)H(12), C-70-CENTER-DOT-12C(6)H(12), C-60-CENTER-DOT-12CCL(4), C-60-CENTER-DOT-2CHBR(3), C-60-CENTER-DOT-2CHCL(3), C-60-CENTER-DOT-2H(2)CCL(2), Zeitschrift fur anorganische und allgemeine Chemie, 621(1), 1995, pp. 14-18
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
1
Year of publication
1995
Pages
14 - 18
Database
ISI
SICI code
0044-2313(1995)621:1<14:SACOTF>2.0.ZU;2-P
Abstract
By crystallization of fullerenes from non-polar solvents (C6H12, CCl4, CHBr3, CHCl3 H2CCl2) compounds of the following compositions were obt ained: C-60 (.) 12C(6)H(12), C-70 (.) 12C(6)H(12), C-60 (.) 12CCl(4), C-60 (.) 2CHCl(3), C-60 (.) 2CHBr(3) and C-60 (.) 2H(2)CCl(2). Lattice parameters have been determined by X-ray diffraction of powder sample s; according to single-crystal examinations on C-60 (.) 12C(6)H(12), C -60 (.) 12CCl(4) and C-60 (.) 2CHBr(3) the fullerene is orientationall y disordered. C-60 (.) 12C(6)H(12), kubisch, a = 28,167(1) Angstrom; C -70 (.) 12C(6)H(12), kubisch, a = 28,608(2) Angstrom; C-60 (.) 12CCl(4 ), kubisch, a = 27,42(1) Angstrom; C-60 (.) 2CHBr(3), hexagonal, a=10, 212(1), c=10,209(1) Angstrom; C-60 (.) 2CHCl(3), hexagonal, a=10,08(1) , c=10,11(2) Angstrom;C-60 (.) 2H(2)CCl(2), tetragonal, a=16,400(1) An gstrom, c=11,645(7) Angstrom.