NON-OXO VANADIUM(IV) COMPLEXES WITH TRIDE NTATE DIACIDIC LIGANDS - MOLECULAR-STRUCTURE OF BIS[2.2'-DIHYDRORY-AZOBENZENATO(2-)]VANADIUM(IV)

Authors
LUDWIG E HEFELE H UHLEMANN E WELLER F KLAUI W
Citation
E. Ludwig et al., NON-OXO VANADIUM(IV) COMPLEXES WITH TRIDE NTATE DIACIDIC LIGANDS - MOLECULAR-STRUCTURE OF BIS[2.2'-DIHYDRORY-AZOBENZENATO(2-)]VANADIUM(IV), Zeitschrift fur anorganische und allgemeine Chemie, 621(1), 1995, pp. 23-28
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
1
Year of publication
1995
Pages
23 - 28
Database
ISI
SICI code
0044-2313(1995)621:1<23:NVCWTN>2.0.ZU;2-S
Abstract
By the reaction of tris (acetylacetonato)vanadium(III) with tridentate diacidic ligands non-ore vanadium(IV) complexes of these ligands were synthesized. The complexes were characterized by mass spectrometry. E lectrochemical studies show that the complexes are reversibly oxidized or reduced. Bis[2,2'dihydroxy-azobenzenato(2 -)]vanadium(IV) has a di storted trigonal-prismatic structure. Crystallographic data see ''Inha ltsubersicht''.