STRUCTURES WITH ALB2-TYPE AND CEMG2SI2-TY PE UNITS - THE COMPOUNDS EU3PD4AS4, CA4PD5P5, AND CA5PD6P6

Citation
D. Johrendt et A. Mewis, STRUCTURES WITH ALB2-TYPE AND CEMG2SI2-TY PE UNITS - THE COMPOUNDS EU3PD4AS4, CA4PD5P5, AND CA5PD6P6, Zeitschrift fur anorganische und allgemeine Chemie, 621(1), 1995, pp. 57-62
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
1
Year of publication
1995
Pages
57 - 62
Database
ISI
SICI code
0044-2313(1995)621:1<57:SWAACP>2.0.ZU;2-C
Abstract
The new compounds Eu3Pd4As4, Ca4Pd5P5, and Ca5Pd6P6 (space groups and lattice constants see ''Inhaltsubersicht'') have been prepared by heat ing mixtures of the elements. Their structures were determined by mean s of single-crystal Xray methods and contain exclusively units, which are characteristic for the AIB(2)- and CeMg2Si2-type. The non-metal at oms are isolated from each other or connected to pairs; the ratio betw een these two kinds can be interpreted by ionic splittings of the form ulas.