SYNTHESIS AND PROPERTIES OF N,N-DIALKYL-A LLYLAMINOBORANES AND N,N-DIMETHYLAMINOPROPYLBORANE

Authors
THIELE KH KURZHALS R DUMICHEN U
Citation
Kh. Thiele et al., SYNTHESIS AND PROPERTIES OF N,N-DIALKYL-A LLYLAMINOBORANES AND N,N-DIMETHYLAMINOPROPYLBORANE, Zeitschrift fur anorganische und allgemeine Chemie, 621(1), 1995, pp. 97-100
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
1
Year of publication
1995
Pages
97 - 100
Database
ISI
SICI code
0044-2313(1995)621:1<97:SAPONL>2.0.ZU;2-A
Abstract
Complexes of the type H3B<--NR(2)(CH2CH=CH2) (R=CH3 I, C2H5 II) are fo rmed by reaction of Li[BH4] with dialkylallylammonium salts. By additi on of AlCl3 I can be transformed into the chelate-stabilized N,N-dimet hyl-amino-propylborane H2B-CH2-CH2-CH2-NMe(2) III. The i.r.-, H-1, C-1 3-n.m.r. and mass-spectra of I - III are reported and discussed.