CRYSTAL AND MOLECULAR-STRUCTURE OF ETHYLCYCLOPENTADIENYL)TITANA(IV)-CYCLOHEXASULFANE, TI(ETA(5)-C5H4CH3)(2)S-5

Authors
KLOURAS N DEMAKOPOULOS I TERZIS A RAPTOPOULOU CP
Citation
N. Klouras et al., CRYSTAL AND MOLECULAR-STRUCTURE OF ETHYLCYCLOPENTADIENYL)TITANA(IV)-CYCLOHEXASULFANE, TI(ETA(5)-C5H4CH3)(2)S-5, Zeitschrift fur anorganische und allgemeine Chemie, 621(1), 1995, pp. 113-116
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
1
Year of publication
1995
Pages
113 - 116
Database
ISI
SICI code
0044-2313(1995)621:1<113:CAMOE>2.0.ZU;2-I
Abstract
The crystal and molecular structure of Ti(eta(5)-C5H4CH3)(2)S-5 has be en determined by X-ray diffraction studies. The substance crystallizes in the monoclinic crystal system [a = 6.8642(5), b = 16.507(1), c = 1 3.074(1) Angstrom, beta = 82.407(3)degrees, space group P2(1)/n, Z = 4 ]. The geometry about the titanium atom is a distorted tetrahedron, wi th a (centroid)Ti-(centroid) angle of 131.29 degrees and a S-Ti-S angl e of 93.38 degrees. The six-membered ring TiS5 has a cyclohexane-like chair configuration. The structural results are compared to those for similar type titanium complexes.