M. Kocova et al., COMPOSITION AND TEMPERING OF FE-C AND FE-NI-C FINE PARTICLES PREPAREDBY SPARK EROSION, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 190(1-2), 1995, pp. 259-265
Fe-C and Fe-Ni-C powders prepared by spark synthesis from pure Fe, Fe-
Ni and C as electrodes were investigated. They exhibit a wide variety
of particles differing in form, size and phase composition. The as-pre
pared powders consist of graphite, carbides, alpha- and gamma-Fe, non-
magnetic phases and a new ferromagnetic component. Carbides dominate a
mong the ferromagnetic phases. The fractions exhibiting superparamagne
tic behaviour contain fine Fe and Fe-C particles in graphite. Changes
in the phase composition due to tempering at elevated temperatures lea
d to the Fe-C equilibrium.