Dh. Kwon et al., EFFECTS OF HEAT-TREATMENT ON TA2O5 SENSING MEMBRANE FOR LOW DRIFT ANDHIGH-SENSITIVITY PH-ISFET, Sensors and actuators. B, Chemical, 34(1-3), 1996, pp. 441-445
This paper presents a new approach for reducing the drift and improvin
g the sensitivity of a pH-ISFET by varying the heat treatment conditio
n of the Ta2O5 sensing membrane. A Ta2O5 pH-ISFET which was heat-treat
ed at various temperatures, showed very different sensing characterist
ics such as sensitivity, long-term drift, etc. When heat-treated in O-
2 ambient at 400 degrees C for 1 h, Ta2O5 pH-ISFET showed low drift, w
hich is maybe related to a densification effect of the film in an amor
phous state with a low leakage current. Furthermore, the Ta2O5 pH-ISFE
T which was heat-treated in O-2, showed good sensitivity, which is may
be associated with an increase of O-sites at the surface. The Ta2O5 pH
-ISFET fabricated by the above method showed good linearity, high sens
itivity (58-59 mV) over a wide pH range (pH 2-12) and low long-term dr
ift (0.03-0.05 pH/day).