An analysis of the nature of optical transitions in the (Hg, Cd) Te al
loy system is presented. Free, bound and localized excitons are the or
igin of the main luminescence lines, whereas for very narrow gap mater
ial (fitting the 10 mu m region) plasma transitions dominate. Special
attention is paid to the luminescence at high excitation levels, where
a distinction between plasma transitions and exciton-exciton scatteri
ng becomes possible for different samples. The results concerning the
gain mechanisms are discussed together with experimental results obtai
ned from injection luminescence.