CRYSTAL-STRUCTURE OF [CP(ASTERISK)BBR][AL BR4]

Citation
C. Dohmeier et al., CRYSTAL-STRUCTURE OF [CP(ASTERISK)BBR][AL BR4], Journal of organometallic chemistry, 487(1-2), 1995, pp. 127-130
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
487
Issue
1-2
Year of publication
1995
Pages
127 - 130
Database
ISI
SICI code
0022-328X(1995)487:1-2<127:CO[B>2.0.ZU;2-T
Abstract
The spectroscopic characterization of the cation [CpBBr](+) from 1979 is now followed by its structural determination with the help of X-ra y methods. The B-C-distance with 168 pm is in the same range as that o f carboranes. The methyl groups of the Cp-ring are bent in the direct ion of the boron atom.