PREPARATION, ISOLATION AND CHEMICAL-REACTIVITY OF THE ALPHA-CF3-PROPARGYLIUM ION STABILIZED BY A HETEROBIMETALLIC [CO-MO] CLUSTER

Authors
KONDRATENKO MA MALEZIEUX B GRUSELLE M BONNETDELPON D BEGUE JP
Citation
Ma. Kondratenko et al., PREPARATION, ISOLATION AND CHEMICAL-REACTIVITY OF THE ALPHA-CF3-PROPARGYLIUM ION STABILIZED BY A HETEROBIMETALLIC [CO-MO] CLUSTER, Journal of organometallic chemistry, 487(1-2), 1995, pp. 15-17
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
487
Issue
1-2
Year of publication
1995
Pages
15 - 17
Database
ISI
SICI code
0022-328X(1995)487:1-2<15:PIACOT>2.0.ZU;2-A
Abstract
The synthesis of a diastereomeric alpha-CF3 derivative of a propargyli c alcohol complexed in a hetero-bimetallic [Co-Mo] cluster is describe d. By the action of HBF4 on the alcohol, one variety of complexed prop argylium ion is formed.