SYNTHESIS AND CHARACTERIZATION OF [PYRH(SALEN)ADAM], AN ADAMANTYL RH-III COMPLEX CONTAINING BIS(SALICYLALDEHYDE)ETHYLENDIIMINATE AS EQUATORIAL LIGAND

Authors
DREOSGARLATTI R GEREMIA S RANDACCIO L RUFFINI S TAUZHER G
Citation
R. Dreosgarlatti et al., SYNTHESIS AND CHARACTERIZATION OF [PYRH(SALEN)ADAM], AN ADAMANTYL RH-III COMPLEX CONTAINING BIS(SALICYLALDEHYDE)ETHYLENDIIMINATE AS EQUATORIAL LIGAND, Journal of organometallic chemistry, 487(1-2), 1995, pp. 24-26
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
487
Issue
1-2
Year of publication
1995
Pages
24 - 26
Database
ISI
SICI code
0022-328X(1995)487:1-2<24:SACO[A>2.0.ZU;2-Z
Abstract
The determination of the X-ray structure and formation constant of a R h-III organometallic complex containing bis(salicylaldehyde)ethylendii minate [(pyridine)Rh(salen)(adamantyl)], revealed a cis-influence on t he axial metal-nitrogen bond significantly greater than that found in the analogous dimethylglyoximate. Comparison of the formation constant s suggests that the stability of the hexacoordinate species with respe ct to the pentacoordinate species in Rh complexes is greater than that for Co complexes.