In the size distribution of ionized helium clusters produced by electr
on impact ionization of very large neutral clusters (N > 10(5) atoms),
He-4(+) is the most abundant small cluster ion. This observation has
recently received considerable attention, since in theoretical calcula
tions no specially stable structure for the tetramer ion could be foun
d. Measurements of the photoabsorption cross section and of the fragme
nt kinetic energy release now indicate that this 'magic' He-4(+) is in
a metastable electronically excited state.