THE PHOTOELECTRON-SPECTRUM OF THIAZYL CYANIDE, NSCN

Authors
ALLAF AW JOHNSTON RL SUFFOLK RJ
Citation
Aw. Allaf et al., THE PHOTOELECTRON-SPECTRUM OF THIAZYL CYANIDE, NSCN, Chemical physics letters, 233(1-2), 1995, pp. 33-35
Citations number
14
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
233
Issue
1-2
Year of publication
1995
Pages
33 - 35
Database
ISI
SICI code
0009-2614(1995)233:1-2<33:TPOTCN>2.0.ZU;2-#
Abstract
Thiazyl cyanide, NSCN, has been produced in a flow system by passing t hiazyl chloride, NSCl, over heated silver cyanide, AgCN. The He I phot oelectron spectrum of NSCN shows prominent bands at 11.33, 13.52, 14.0 2 and 14.97 eV, in good agreement with ab initio SCF molecular orbital calculations. The first ionisation of NSCN is attributed to the remov al of an electron from the weakly bonding 8a' HOMO,