Mg. Steinmetz et Q. Chen, PHOTOCHEMICAL [1,3-C] MIGRATION OF A BRIDGEHEAD SILANORBORNENE, Journal of the Chemical Society, Chemical Communications, (2), 1995, pp. 133-134
Direct photolysis (214 nm) of 1-methyl-1-silabicyclo[2.2.1]hept-2-ene
in alcohols results in [1,3-C-7] migration to produce 3-alkoxy-3-methy
l-3-silabicyclo [4.1.O]heptanes.