B. Coutant et al., H D EXCHANGE OF ORGANOSILANES CATALYZED BY HETEROGENIZED ZIRCONIUM HYDRIDE COMPLEXES/, Journal of the Chemical Society, Chemical Communications, (2), 1995, pp. 137-138
Silica supported zirconium hydride complexes activate stoichiometrical
ly and catalytically the SI-H bond of primary, secondary and tertiary
organosilanes, R(4-x)SiH(x), R = alkyl, aryl.