SYNTHESIS AND CRYSTAL-STRUCTURE OF [K(C12H24O6)][U(ETA-C7H7)(2)], THEFIRST CYCLOHEPTATRIENYL SANDWICH COMPOUND

Authors
ARLIGUIE T LANCE M NIERLICH M VIGNER J EPHRITIKHINE M
Citation
T. Arliguie et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF [K(C12H24O6)][U(ETA-C7H7)(2)], THEFIRST CYCLOHEPTATRIENYL SANDWICH COMPOUND, Journal of the Chemical Society, Chemical Communications, (2), 1995, pp. 183-184
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
2
Year of publication
1995
Pages
183 - 184
Database
ISI
SICI code
0022-4936(1995):2<183:SACO[T>2.0.ZU;2-6
Abstract
The title compound was prepared by treating a mixture of UCl4 and K wi th C7H8 or by reacting UCl4 with KC7H9; the crystal structure shows th at the two C7H7 ligands are planar, parallel and perpendicular to the linear axis defined by the uranium atom and the ring centroids.