Tl. Mccormick et al., THE CHARACTERIZATION OF STRAIN, IMPURITY CONTENT, AND CRUSH STRENGTH OF SYNTHETIC DIAMOND CRYSTALS, Journal of materials research, 12(1), 1997, pp. 253-263
This study addresses the correlation of the macroscopic and microscopi
c characteristics of synthetic diamond crystals produced by high press
ure, high temperature conditions. Microscopic properties were characte
rized using Raman spectroscopy, birefringence, and photoluminescence (
PL). Macroscopic properties characterized included inclusion content a
nd crush force. Raman measurements detected measurable stress shifts i
n only two samples. The PL measurements indicated an increased presenc
e of the H3 center in areas of high strain. The absence of the H3 cent
er and the presence of the N-V PL center was correlated to lower avera
ge crush force. A hierarchy has been developed that relates microscopi
c properties to average crush force.