This review presents research in the area of polymeric coatings develo
ped for protecting low earth orbit (LEG) space structures from atomic
oxygen. Following a brief description of the LEO environment, ground-b
ased simulation facilities for atomic oxygen and evaluation of protect
ive coatings are discussed. Atomic oxygen resistant coatings based on
different polymeric systems such as fluorinated polymers, silicones, p
oly(carborane-siloxane)s and decarborane-based polymers are presented.
Finally, the performances of different coating systems are compared a
nd the scope for further research to improve the performance of some o
f the coating systems is discussed.