ENYNE CYCLIZATION BY PHOTOINDUCED ELECTRON-TRANSFER (PET) PROMOTED IN-SITU GENERATED ELECTROPHILIC SELENIUM SPECIES - A NEW CARBOCYCLISATION STRATEGY

Authors
PANDEY G SEKHAR BBVS
Citation
G. Pandey et Bbvs. Sekhar, ENYNE CYCLIZATION BY PHOTOINDUCED ELECTRON-TRANSFER (PET) PROMOTED IN-SITU GENERATED ELECTROPHILIC SELENIUM SPECIES - A NEW CARBOCYCLISATION STRATEGY, Tetrahedron, 51(5), 1995, pp. 1483-1494
Citations number
46
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
5
Year of publication
1995
Pages
1483 - 1494
Database
ISI
SICI code
0040-4020(1995)51:5<1483:ECBPE(>2.0.ZU;2-J
Abstract
A new strategy for the carbocyclisation of enynes by PET initiated in situ generated electrophilic selenium species from diphenyldiselenide (PhSeSePh) is reported. The structure of the reactive selenium interme diate is also discussed.