D. Braun et Kh. Bahlig, BENZYLCELLULOSE AS A THERMOPLAST .2. STAB ILIZATION AND PLASTICIZATION, Die Angewandte makromolekulare Chemie, 224, 1995, pp. 61-71
By addition of a stabilizer (4-benzyloxyphenol) the oxidative thermal
decomposition of benzylcellulose during melt processing was reduced. T
he minimum stabilizer concentration was 5 wt.-%. Plastification with d
iethyl phthalate reduced the glass transition temperature and the proc
essing temperature and imparted softness and flexibility of the inhere
ntly brittle benzylcellulose. The required plasticiser concentration (
5-10 wt.-%) is lower than that required for other cellulose ethers lik
e ethylcellulose (10-20 wt.-%) or cellulose acetates (20-30 wt.-%).