SML2 OR SML3 MEDIATED ALDOL-TYPE REACTION OF ALPHA-HALO KETONES WITH ALIPHATIC ALPHA-DIKETONES - FACILE SYNTHESIS OF 2-HYDROXY-1,4-DIKETONES

Authors
ARIME T TAKAHASHI H KOBAYASHI S YAMAGUCHI S MORI N
Citation
T. Arime et al., SML2 OR SML3 MEDIATED ALDOL-TYPE REACTION OF ALPHA-HALO KETONES WITH ALIPHATIC ALPHA-DIKETONES - FACILE SYNTHESIS OF 2-HYDROXY-1,4-DIKETONES, Synthetic communications, 25(3), 1995, pp. 389-393
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
3
Year of publication
1995
Pages
389 - 393
Database
ISI
SICI code
0039-7911(1995)25:3<389:SOSMAR>2.0.ZU;2-L
Abstract
The title reaction proceeds in the presence of SmI2 or SmI3 in tetrahy drofuran at room temperature, probably via intermediary formation of s amarium enolates from alpha-halo ketones, to give 2-hydroxy-1,4-diketo nes in good yields.