PULSED-LASER TERPOLYMERIZATION OF STYRENE, METHYL-METHACRYLATE AND METHYL ACRYLATE

Authors
SCHOONBROOD HAS VANDENREIJEN B DEKOCK JBL MANDERS BG VANHERK AM GERMAN AL
Citation
Has. Schoonbrood et al., PULSED-LASER TERPOLYMERIZATION OF STYRENE, METHYL-METHACRYLATE AND METHYL ACRYLATE, Macromolecular rapid communications, 16(2), 1995, pp. 119-124
Citations number
14
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular rapid communications → ACNP
ISSN journal
10221336
Volume
16
Issue
2
Year of publication
1995
Pages
119 - 124
Database
ISI
SICI code
1022-1336(1995)16:2<119:PTOSMA>2.0.ZU;2-K
Abstract
The propagation rate coefficient of the terpolymerization of styrene, methyl methacrylate and methyl acrylate in bulk was successfully deter mined at three different monomer compositions. The temperature was var ied between 18 and 80 degrees C. The resulting data at 50 degrees C we re not in agreement with predictions according to the terminal model w ith binary reactivity ratios that have been determined by fitting copo lymer composition data with the terminal model. This indicates that he re also the penultimate unit affects the kinetics.