Sv. Shilov et al., FOURIER-TRANSFORM INFRARED STUDY OF THE SWITCHING PROCESS IN A FERROELECTRIC LIQUID-CRYSTALLINE POLYMER, Macromolecular rapid communications, 16(2), 1995, pp. 125-130
The implementation of the step-scan technique on our FT-IR spectromete
r enabled us to follow the electric-field induced reorientation dynami
cs of different molecular segments of a ferroelectric liquid crystalli
ne polymer on a sub-millisecond time scale. It was detected that not o
nly the mesogen but also the spacer and at least part of the backbone
take part in the reorientation process.