INORGANIC QUADRICYCLANES - SYNTHESIS AND CHARACTERIZATION OF NOVEL SULFUR-BRIDGED AND SELENIUM-BRIDGED MIXED CR FE CLUSTERS, CRFE2(CO)(10)E(4) (E=S,SE) - CRYSTAL-STRUCTURE OF CRFE2(CO)(10)SE-4/
P. Mathur et al., INORGANIC QUADRICYCLANES - SYNTHESIS AND CHARACTERIZATION OF NOVEL SULFUR-BRIDGED AND SELENIUM-BRIDGED MIXED CR FE CLUSTERS, CRFE2(CO)(10)E(4) (E=S,SE) - CRYSTAL-STRUCTURE OF CRFE2(CO)(10)SE-4/, Organometallics, 16(1), 1997, pp. 142-144
The new clusters CrFe2(CO)(10)E(4) (E = S, 1; E = Se, 2) have been iso
lated from the room temperature reactions of Fe-2(CO)(6)(mu-E(2)) and
Cr(CO)(5)(THF), and the structure of CrFe2(CO)(10)Se-4 has been establ
ished by single-crystal X-ray diffraction methods.