Tris(trimethylsilyl)silylmagnesium bromide, obtained in situ from tris
(trimethylsilyl)silyllithium and magnesium bromide, reacts with aceton
e, pivalaldehyde, or 2,4,6-trimethylbenzaldehyde to give the (1-hydrox
yalkyl)tris (trimethylsilyl)silanes (Me(3)Si)(3)SiC(OH)Me(2) (1a), (Me
(3)Si)(3)CH(OH)tBu (1b), and (Me(3)Si)(3)SiCH(OH)Mes (1c), resp. After
deprotonation with methyllithium in ether at -78 degrees C 1a-c elimi
nate trimethylsilanolate according to a modified Peterson mechanism to
form transient silenes (Me(3)Si)(2)Si=CR(1)R(2) (6a: R(1)= R(2) = Me;
6b: R(1) = H, R(2) = tBu; 6C: Ri = H, R(2) = Mes). In the absence of
trapping agents these silenes dimerize, 6a leading to the linear dimer
1-isopropenyl-2-isopropyl-1,1,2,2-tetrakis methylsilyl)disilane (7) a
nd 6b giving the head-to-head cyclodimerization product 3,4-di-tert-bu
ty1-1,1,2,2-tetrakis(trimethylsilyl) -1,2-disilacyclobutane (8), where
as 6c in a very unusual cyclodimerization step affords ,3-tetrakis(tri
meth-ylsilyl)-2,3-disilanaphthalene (9). Compound 9 is the result of a
n unexpected [2 + 4] reaction, in which the silene formally acts as th
e monoene and - involving the aromatic substituent - simultaneously al
so as the diene. The reaction of 1a-c with methyllithium in THF at low
temperature initiates 1,3-Si,O-trimethylsilyl migrations leading to (
trimethylsiloxy)[bis (trimethylsilyl) silyl] alkanes (Me(3)Si)(2)SiH-C
R(1)R(2)OSiMe(3) 3a-c. Reaction of 1a-c with an excess of methyllithiu
m, tert-butyllithium, or phenyllithium, leads to trisilanes (Me(3)Si)(
2)-SiR(3)-CHR(1)R(2) 11a-e, formed by the addition of the organolithiu
m reagent to the Si=C bond of the transient silenes 6a-c. Deprotonatio
n of 1b and 1c in the presence of 2,3-dimethyl-1,3-butadiene gives the
[2 + 4] cycloadducts 6-tert-butyl-3,4-dimethyl- 1,1-bis(trimethylsily
l)-1-sila-3-cyclohexene (12a) and 6-mesityl-3,4-dimethyl-1,1-bis(trime
thylsi lyl)-1-sila-3-cyclohexene (12b), For 8 and 9 the results of the
X-ray analyses are given.