High spectral resolution imagery produced by imaging spectrometers ena
bles the discrimination of geologic materials whose surface expression
is subpixel in scale. Moreover, the use of such data makes it possibl
e to distinguish materials which are characterized only by subtle diff
erences in the spectral continuum. We define the ''continuum'' as the
reflectance or radiance spanning the space between spectral features.
The capability to distinguish subpixel targets will prove invaluable i
n studies of the geology of the Earth and planets from airborne and sp
aceborne imaging spectrometers. However, subpixel targets can only be
uniquely identified in a truly optimal sense through the application o
f data reduction techniques that model the spectral contribution of bo
th target and background materials. Two such techniques are utilized h
erein. They are a spectral mixture analysis approach and a low probabi
lity detection routine based on orthogonal subspace projection. These
techniques were applied to the problem of detecting two different volc
anic tuff units, one basaltic and one rhyolitic, in two different scen
es of data measured by the airborne visible/infrared imaging spectrome
ter (AVIRIS). These tuff units have limited exposures from an overhead
perspective and have spectral signatures which differ from those of b
ackground materials only in terms of subtle slope changes in the refle
ctance continuum. Of the two approaches, it was found that the low pro
bability detection algorithm was more effective in highlighting those
pixels that contained the target tuff units while suppressing the resp
onse of undesired background materials.