Analysing the electronic structure of silicon crystals, both regular a
nd doped with erbium, we conclude that the erbium ion tends to form bo
nds with three ligands. The role of oxygen in the passivation of the f
ormed dangling bond is discussed. Studies of the electric, magnetic, a
nd optical properties of Si : Er grown by the Czochralsky method show
that the Er2O complexes existing in these crystals become electrically
and optically active only in the case when they locate near the shall
ow donor (phosphorus).