PREPARATION OF ADAMANTYL SULFIDES WITH [BIS(1-ADAMANTANECARBOXY)IODO]ARENES AND DISULFIDES

Authors
TOGO H MURAKI T YOKOYAMA M
Citation
H. Togo et al., PREPARATION OF ADAMANTYL SULFIDES WITH [BIS(1-ADAMANTANECARBOXY)IODO]ARENES AND DISULFIDES, Synthesis, (2), 1995, pp. 155-157
Citations number
49
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
2
Year of publication
1995
Pages
155 - 157
Database
ISI
SICI code
0039-7881(1995):2<155:POASW[>2.0.ZU;2-G
Abstract
Irradiation of [bis(1-adamantanecarboxy)iodo]arenes with a high-pressu re mercury lamp in the presence of disulfides gives the corresponding adamantyl sulfides in high yields. This reaction proceeds via the radi cal decarboxylation of [bis(1-adamantanecarboxy)iodo]arenes followed b y S(H)2 reaction of the carbon radical on the disulfide.