MANGANESE PORPHYRIN-CATALYZED HOMOGENEOUS AQUEOUS OXIDATION OF ORGANIC-MOLECULES BY MAGNESIUM MONOPEROXYPHTHALATE (MMPP)

Authors
ZHENG TC RICHARDSON DE
Citation
Tc. Zheng et De. Richardson, MANGANESE PORPHYRIN-CATALYZED HOMOGENEOUS AQUEOUS OXIDATION OF ORGANIC-MOLECULES BY MAGNESIUM MONOPEROXYPHTHALATE (MMPP), Tetrahedron letters, 36(6), 1995, pp. 837-840
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
6
Year of publication
1995
Pages
837 - 840
Database
ISI
SICI code
0040-4039(1995)36:6<837:MPHAOO>2.0.ZU;2-R
Abstract
Magnesium monoperoxyphthalate (MMPP) oxidizes a variety of organic mol ecules in neutral homogeneous aqueous solutions at room temperature. A water-soluble porphyrin complex, rakis(4-N-methylpyridyl)porphyrinato manganese(III) chloride, Mn(III)TMPyP(4) Cl, acts as an efficient cata lyst for the epoxidation and hydroxylation of water-soluble hydrocarbo ns.