SYNTHESIS OF A PERACETYLATED STEREOISOMER OF DE-ROSAS CALDITOL - SOMEQUESTIONS ABOUT THE CORRECTNESS OF THE ORIGINAL STRUCTURE ASSIGNED TOTHIS NATURAL PRODUCT

Authors
FAIRBANKS AJ SINAY P
Citation
Aj. Fairbanks et P. Sinay, SYNTHESIS OF A PERACETYLATED STEREOISOMER OF DE-ROSAS CALDITOL - SOMEQUESTIONS ABOUT THE CORRECTNESS OF THE ORIGINAL STRUCTURE ASSIGNED TOTHIS NATURAL PRODUCT, Tetrahedron letters, 36(6), 1995, pp. 893-896
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
6
Year of publication
1995
Pages
893 - 896
Database
ISI
SICI code
0040-4039(1995)36:6<893:SOAPSO>2.0.ZU;2-5
Abstract
Comparison of the C-13 nmr spectrum of the nonacetate of a synthetic s tereoisomer of calditol with that of the nonacetate of the natural pro duct, combined with a comparison of the C-13 nmr spectrum of the perac etate of a hexitol derived from calditol with all known peracetates of open chain hexitols, invalidates the originally proposed structure.