UNEXPECTED OUTCOME OF NBCL5-PROMOTED SAKURAI REACTION - MECHANISTIC IMPLICATIONS RELEVANT TO C4H7+ SPECIES

Authors
MAETA H NAGASAWA T HANDA Y TAKEI T OSAMURA Y SUZUKI K
Citation
H. Maeta et al., UNEXPECTED OUTCOME OF NBCL5-PROMOTED SAKURAI REACTION - MECHANISTIC IMPLICATIONS RELEVANT TO C4H7+ SPECIES, Tetrahedron letters, 36(6), 1995, pp. 899-902
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
6
Year of publication
1995
Pages
899 - 902
Database
ISI
SICI code
0040-4039(1995)36:6<899:UOONSR>2.0.ZU;2-H
Abstract
Use of NbCl5 in the Sakurai reaction gave an unexpected outcome. Allyl silane reacted with aldehyde in 2:1-stoichiometry with concomitant for mation of a cyclopropane ring. Mechanistic implications of this anomal ous reaction related to C4H7+ species are discussed based on the exper imental and theoretical (ab initio) studies.