INTERNAL ACTIVATION OF ACRYLATE-TYPE DIENOPHILES IN DIELS-ALDER REACTIONS

Authors
Citation
T. Kan et Y. Ohfune, INTERNAL ACTIVATION OF ACRYLATE-TYPE DIENOPHILES IN DIELS-ALDER REACTIONS, Tetrahedron letters, 36(6), 1995, pp. 943-946
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
6
Year of publication
1995
Pages
943 - 946
Database
ISI
SICI code
0040-4039(1995)36:6<943:IAOADI>2.0.ZU;2-O
Abstract
Diels-Alder reactions of less reactive acrylate-type dienophiles with dienes were achieved by replacing its ester counterpart to a pentafluo rophenyl group, which remarkably enhanced the reactivity of the dienop hiles to give the corresponding cycloadducts in excellent yields with a high stereoselectivity.