DIASTEREOSELECTIVE INTRAMOLECULAR META-CYCLOADDITION OF AN ARENE TO AN OLEFIN

Authors
ZHANG C GUO XC SHEN XM XU YF
Citation
C. Zhang et al., DIASTEREOSELECTIVE INTRAMOLECULAR META-CYCLOADDITION OF AN ARENE TO AN OLEFIN, Synthetic communications, 25(5), 1995, pp. 775-781
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
5
Year of publication
1995
Pages
775 - 781
Database
ISI
SICI code
0039-7911(1995)25:5<775:DIMOAA>2.0.ZU;2-W
Abstract
The photo-induced intramolecular meta-cycloaddition of bichromophore 1 gave diastereoselectively tur, adducts 2 and 3. The observed stereoch emistry of cycloaddition is rationalized in terms of hydrogen bond eff ect Induced by the 3-hydroxy group in the 5-phenylpent-1-ene skeleton.