L. Yiping et al., HEAT-TREATMENT EFFECTS ON STRUCTURAL AND MAGNETIC-PROPERTIES OF FINE FE-B PARTICLES, Journal of magnetism and magnetic materials, 164(3), 1996, pp. 357-366
The structural and magnetic properties of fine Fe-B particles with a s
ize of about 50 nm and B concentrations of 5, 14, and 17 at.% were stu
died in as-prepared samples and after annealing in vacuum and in H-2 a
tmosphere. The samples annealed in vacuum were found to be dominated b
y alpha-Fe in the high B concentrations. Oxide components appear in th
e particles with low B content. Boron is found to prevent oxidation of
the as-made samples and promote the formation of mixed valence oxides
in the crystallized samples.