REDUCTIVE CARBONYLATIONS REACTIONS OF PRIMARY PHOSPHINE MONO-ETA-CYCLOPENTADIENYLTUNGSTEN(V) COMPOUNDS

Authors
GREEN MLH MORISE XM HAMILTON AH CHERNEGA AN
Citation
Mlh. Green et al., REDUCTIVE CARBONYLATIONS REACTIONS OF PRIMARY PHOSPHINE MONO-ETA-CYCLOPENTADIENYLTUNGSTEN(V) COMPOUNDS, Journal of organometallic chemistry, 488(1-2), 1995, pp. 73-78
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
488
Issue
1-2
Year of publication
1995
Pages
73 - 78
Database
ISI
SICI code
0022-328X(1995)488:1-2<73:RCROPP>2.0.ZU;2-2
Abstract
The new tungsten (IV) compounds [W(eta-(C5H4Pr)-Pr-i)Cl-3(P)(CO)] (whe re P = H2PC3H5, H2PC2H3 or PMe(3)) have been prepared from the corresp onding tungsten (V) compounds [W((eta-(C5H4Pr)-Pr-i)Cl-4(P)] by treatm ent with [Fe-2(CO)(9)] The crystal structures have been determined for the W(IV) compounds with P = H2PC2H5 and PMe(3).