VINYL-PLUS-VINYL COUPLING IN RHODIUM COMPLEXES - FORMATION OF [(C(5)ME(5))RHBR(ETA(3)-SYN-1-METHYLALLYL)] BY REACTION OF [(C(5)ME(5))RHBR2(ME(2)SO)] WITH VINYLMAGNESIUM BROMIDE IN HOMOGENEOUS SOLUTION

Authors
WANG ZQ TURNER ML KUNICKI AR MAITLIS PM
Citation
Zq. Wang et al., VINYL-PLUS-VINYL COUPLING IN RHODIUM COMPLEXES - FORMATION OF [(C(5)ME(5))RHBR(ETA(3)-SYN-1-METHYLALLYL)] BY REACTION OF [(C(5)ME(5))RHBR2(ME(2)SO)] WITH VINYLMAGNESIUM BROMIDE IN HOMOGENEOUS SOLUTION, Journal of organometallic chemistry, 488(1-2), 1995, pp. 11-12
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
488
Issue
1-2
Year of publication
1995
Pages
11 - 12
Database
ISI
SICI code
0022-328X(1995)488:1-2<11:VCIRC->2.0.ZU;2-Z
Abstract
The syn-1-methylallyl complex [(C(5)Me(5))RhBr(eta(3)-CH(2)CHCHMe)] wa s obtained by reaction of [(C(5)Me(5))RhBr2(Me(2)SO)] with vinylmagnes ium bromide, via a vinyl-plus-vinyl coupling. This reaction is related to the vinyl-plus-vinyl coupling reactions of vinyl bromide on rhodiu m particles under Fischer-Tropsch conditions.