A SHORT TOTAL SYNTHESIS OF ESTRONE DERIVATIVES - A NOVEL 1,3-REARRANGEMENT OF AN ALLYLIC NITRO-GROUP

Authors
BARLAAM B BOIVIN J ELKAIM L ELTONFARR S ZARD SZ
Citation
B. Barlaam et al., A SHORT TOTAL SYNTHESIS OF ESTRONE DERIVATIVES - A NOVEL 1,3-REARRANGEMENT OF AN ALLYLIC NITRO-GROUP, Tetrahedron, 51(6), 1995, pp. 1675-1684
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
6
Year of publication
1995
Pages
1675 - 1684
Database
ISI
SICI code
0040-4020(1995)51:6<1675:ASTSOE>2.0.ZU;2-0
Abstract
Racemic 11 beta,14 beta-dihydroxyestrone has been preparared from 6-me thoxytetralone in 5 steps involving a new acid catalysed 1,3-shift of an allylic nitro group.