Light emission spectra from the gap region of a scanning tunneling mic
roscope (STM) have been measured simultaneously with the cross-section
of the surface topography. The spectra consist of two components cent
ered about 1.7 and 2.0 eV. The intensity ratio between these component
s varies as the tip moves along different surface structures on the sa
mple. We have found a correlation between the light emission spectra a
nd the surface topography. We suggest a mechanism that can qualitative
ly explain the observed position-dependent spectra.