REGIOSELECTIVE RING-OPENING OF GLUCOSE DERIVED SPIRO EPOXIDES

Authors
LAY LG NICOTRA F PANZA L RUSSO G
Citation
Lg. Lay et al., REGIOSELECTIVE RING-OPENING OF GLUCOSE DERIVED SPIRO EPOXIDES, Synlett, (2), 1995, pp. 167-168
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
2
Year of publication
1995
Pages
167 - 168
Database
ISI
SICI code
0936-5214(1995):2<167:RROGDS>2.0.ZU;2-6
Abstract
Spiro epoxides 2 derived from glucose can be opened either in acidic o r basic conditions with opposite regioselectivity. Some examples with different nucleophiles are described. The procedure give access to int ermediates which can be used in glycosidation reactions or in the synt hesis of modified ketosugars.