SILYLATION OF PHENYL SUBSTITUENTS BY ME(3)SICL LI/THF SYSTEMS IN METHYLPHENYLSILYLENE UNITS OF POLYSILANES - SPECTROSCOPIC (H-1, C-13, SI-29-NMR) STUDIES OF IMETHYLSILYL)CYCLOHEX-1-ENYL]HEPTAMETHYLTRISILANE/

Authors
REYX D MARTINS JM CAMPISTRON I HUET F
Citation
D. Reyx et al., SILYLATION OF PHENYL SUBSTITUENTS BY ME(3)SICL LI/THF SYSTEMS IN METHYLPHENYLSILYLENE UNITS OF POLYSILANES - SPECTROSCOPIC (H-1, C-13, SI-29-NMR) STUDIES OF IMETHYLSILYL)CYCLOHEX-1-ENYL]HEPTAMETHYLTRISILANE/, Bulletin de la Societe chimique de France, 131(9), 1994, pp. 1007-1014
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
131
Issue
9
Year of publication
1994
Pages
1007 - 1014
Database
ISI
SICI code
0037-8968(1994)131:9<1007:SOPSBM>2.0.ZU;2-4
Abstract
rimethylsilyl)cyclohex-1-enyl]heptamethyltrisilane was characterized i n solution using spectr oscopic methods (UV, IR, NMR (H-1 C-13, Si-29) ). The assignments of the H-1 NMR, C-13 NMR and Si-29 NMR resonances b y use of irradiative and C-13/H-1 and Si-29/H-1 two-dimensional NMR te chniques are described. The relationship between NMR characteristics a nd electronic structure is discussed.