GENERAL ROUTES TO FUNCTIONAL ORGANOTIN TRICHLORIDES AND TRIALKOXIDES INVOLVING THE TRICYCLOHEXYLSTANNYL GROUP

Authors
JOUSSEAUME B LAHCINI M RASCLE MC
Citation
B. Jousseaume et al., GENERAL ROUTES TO FUNCTIONAL ORGANOTIN TRICHLORIDES AND TRIALKOXIDES INVOLVING THE TRICYCLOHEXYLSTANNYL GROUP, Organometallics, 14(2), 1995, pp. 685-689
Citations number
74
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
2
Year of publication
1995
Pages
685 - 689
Database
ISI
SICI code
0276-7333(1995)14:2<685:GRTFOT>2.0.ZU;2-R
Abstract
New functional organotin trialkoxides have been prepared in two steps from the corresponding organotricyclohexyltins, which were obtained by coupling an organometal species with tricyclohexyltin chloride, by re action of (tricyclohexylstannyl)lithium with an organic halide, or by hydrostannation of alkenes. Treatment of organotricyclohexyltins with tin tetrachloride gave the corresponding organotin trichlorides which were further transformed into functional organotin trialkoxides.