AN UNUSUALLY LARGE VALUE OF (1)J(P-31,P-31) FOR A SOLID TRIPHENYLPHOSPHINE PHOSPHADIAZONIUM CATIONIC COMPLEX - DETERMINATION OF THE SIGN OFJ FROM 2D SPIN-ECHO EXPERIMENTS
K. Eichele et al., AN UNUSUALLY LARGE VALUE OF (1)J(P-31,P-31) FOR A SOLID TRIPHENYLPHOSPHINE PHOSPHADIAZONIUM CATIONIC COMPLEX - DETERMINATION OF THE SIGN OFJ FROM 2D SPIN-ECHO EXPERIMENTS, Canadian journal of chemistry, 74(11), 1996, pp. 2372-2377
Phosphorus-31 NMR spectra of a solid triphenylphosphine phosphadiazoni
um salt, [MesNP-PPh(3)][SO3CF3], have been acquired at 4.7 and 9.4 T.
Analysis of the spectra obtained with magic angle spinning indicates
that the two phosphorus nuclei are strongly spin-spin coupled, /(1)J((
PP)-P-31-P-31)/=405(5) Hz, despite the unusually long P-P separation,
r(p,p)=2.625 Angstrom. Two-dimensional spin-echo spectra provide convi
ncing evidence that (1)J(P-31,P-31) is negative. Semi-empirical molecu
lar orbital calculations at the INDO level support the negative sign f
or (1)J(P-31, P-31). A large span, 576 ppm, is observed ior the chemic
al shift tensor of the two-coordinate phosphorus centre (delta(11)=307
ppm, delta(22)=174 ppm, delta(33)=-269 ppm), which is very similar to
the value previously reported for the non-coordinated phosphorus cent
re in the free Lewis acid, [MesNP][AlCl4]. The principal components a
nd orientations of the phosphorus shielding tensors of these compounds
are compared with those calculated for [HNP] and ifs phosphine adduc
t using the ab initio Gauge-including Atomic Orbitals method. The phos
phorus chemical shift tensor of the triphenylphosphine moiety has a re
latively small span of 33 ppm.