PLATINUM-GROUP METAL SCHIFF-BASE COMPLEXES .1. PLATINUM COMPLEXES

Authors
ALALLAF TAK SHEET AZM
Citation
Tak. Alallaf et Azm. Sheet, PLATINUM-GROUP METAL SCHIFF-BASE COMPLEXES .1. PLATINUM COMPLEXES, Polyhedron, 14(2), 1995, pp. 239-248
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
2
Year of publication
1995
Pages
239 - 248
Database
ISI
SICI code
0277-5387(1995)14:2<239:PMSC.P>2.0.ZU;2-5
Abstract
Schiff base ligands (L), prepared from benzaldehyde, salicylaldehyde a nd 2- or 3-aminopyridines or 3-aminoquinoline, have been isolated and reacted with K2PtCl4, cis-[Pt(DMSO)(2)Cl-2], Pt(COD)Cl-2] and [PtL'Cl- 2]2 (L' = C2H4, PEt(3), PPh(3) PMe(2)Ph) in different molar ratios, to yield complexes of general formula [PtLCl(2)](n) (n = 1 or 2) and cis - or trans-[PtLL'Cl-2]. The Schiff bases and their platinum complexes have been characterized physicochemically.