X-RAY CRYSTAL-STRUCTURE OF [NI(ETA(2)-C(NBU(T))CH(SIME(3))(2))CL(PME(3))], THE FIRST STRUCTURALLY CHARACTERIZED ETA(2)-ALKANEIMIDOYL COMPLEX OF NICKEL

Authors
BELDERRAIN TR PANEQUE M POVEDA ML SERNAU V CARMONA E GUTIERREZ E MONGE A
Citation
Tr. Belderrain et al., X-RAY CRYSTAL-STRUCTURE OF [NI(ETA(2)-C(NBU(T))CH(SIME(3))(2))CL(PME(3))], THE FIRST STRUCTURALLY CHARACTERIZED ETA(2)-ALKANEIMIDOYL COMPLEX OF NICKEL, Polyhedron, 14(2), 1995, pp. 323-326
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
2
Year of publication
1995
Pages
323 - 326
Database
ISI
SICI code
0277-5387(1995)14:2<323:XCO[>2.0.ZU;2-1
Abstract
The alkylation of [NiCl2(PMe(3))(2)] with Mg[CH(SiMe(3))(2)]Cl yielded the alkyl dimer [Ni{CH(SiMe(3))(2)}(mu-Cl)(PMe(3))](2) (1), which rea dily inserted CNBu(t) to afford [Ni{eta(2)-C(NBu(t))CH(SiMe(3))(2)}Cl( PMe(3))] (4); spectroscopic and X-ray studies reveal this complex cont ains an eta(2)-alkaneimidoyl ligand.