HELICAL GROUP-12 COORDINATION - THE X-RAY CRYSTAL-STRUCTURE OF A 5-CO-ORDINATE ZINC(II) COMPLEX

Authors
ADATIA T BEYNEK N MURPHY BP
Citation
T. Adatia et al., HELICAL GROUP-12 COORDINATION - THE X-RAY CRYSTAL-STRUCTURE OF A 5-CO-ORDINATE ZINC(II) COMPLEX, Polyhedron, 14(2), 1995, pp. 335-338
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
2
Year of publication
1995
Pages
335 - 338
Database
ISI
SICI code
0277-5387(1995)14:2<335:HGC-TX>2.0.ZU;2-Z
Abstract
The templated diimine-containing complexes, [M(SpyNpy(2))](ClO4)(2).0. 5H(2)O {where M = Zn-II, Cd-II or Hg-II}, exhibit chirality in solutio n (NMR) which is consistent with, and may be diagnostic of, a helical coordination array in these complexes as verified by the X-ray crystal structure of an enantiomer of the zinc(II) derivative.