V. Massardier et al., EXPERIMENTAL-STUDY OF THE INTERACTION OF MAGNESIUM WITH THE REINFORCEMENT IN AL-MG-SI ALLOY ALPHA-ALUMINA PLATELET COMPOSITES, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 191(1-2), 1995, pp. 267-276
The age hardening capacity of composite materials is closely related t
o their processing history. Chemical interactions may take place betwe
en the alloying elements and the reinforcement, leading to reduced str
uctural hardening of the matrix. The aim of this study was to identify
the mechanisms of interaction implied in the solutionizing treatment
of Al-Mg-Si alloys reinforced with a continuous network of alpha-alumi
na platelets. Thermoelectric power measurements, electron microprobe a
nalyses and transmission electron microscopy investigations clearly de
monstrated a decrease in the magnesium content of the solid solution o
f the matrix during the solutionizing treatment. This is the result of
competition between two mechanisms. Magnesium can diffuse through the
entire mass of the material and preferentially along the continuous n
etwork of interfaces created by the interconnected platelets, before l
eaving the composite towards the external surface of the composite. It
can also react to form MgAl2O4 inel at the interface.