Several low-Z refractory materials are evaluated for use as the NIF fi
rst wall in terms of their cost, level of vacuum outgassing, and abili
ty to survive laser light, target emissions and debris, and rigorous d
econtamination. The best performers contain B, C, or both, with B4C be
ing the best overall. It appears possible at this time that plasma-spr
ayed B4C can be fabricated with low enough porosity and cost to be pre
ferred over hot-pressed B4C, the conservative choice.