Photospheric magnetograms and Skylab images in the lines of Ne VI and
Mg VI near 400 Angstrom have been used to study the relation between m
agnetic field topology and solar composition. Although plasma with the
neon-rich photospheric composition is rare in the corona, it always o
ccurs where new flux is emerging. This suggests that the neon richness
of the plasma reflects its recent photospheric origin, not its closed
-loop magnetic topology as has been assumed in the past. Such a ''volc
anic'' process would be consistent with our observations of sunspots,
which have the Ne-rich composition when they lie next to a neutral lin
e where flux is emerging, but have the Mg-rich composition when they a
re surrounded by a ''buffer zone'' of like-polarity flux.