RUTHENIUM CARBONYL CLUSTERS AS CATALYSTS IN THE WATER-GAS SHIFT REACTIONS

Authors
MOYA S SARIEGO R AGUIRRE P SARTORI R DIXNEUF P
Citation
S. Moya et al., RUTHENIUM CARBONYL CLUSTERS AS CATALYSTS IN THE WATER-GAS SHIFT REACTIONS, Bulletin des Societes chimiques belges, 104(1), 1995, pp. 19-25
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
104
Issue
1
Year of publication
1995
Pages
19 - 25
Database
ISI
SICI code
0037-9646(1995)104:1<19:RCCACI>2.0.ZU;2-T
Abstract
The catalytic activity of Ru-3(CO)(9) L(3) (L = arylphosphine) in the WGSR and in the reduction of nitro derivatives to amines is studied. T he same complex is supported in polystyrene-divinylbenzene copolymer ( PSDVB) and the catalytic activity of this heterogeneous material on th e fore mentioned reactions is herein studied. In the same way, Ru-3(CO )(12) is reacted with PSDVB, previously functionalized with 1,2-ethyle nediamine, giving an active catalyst for these reactions.