SELECTIVITY TO N-MONO OR DIALKYLATION IN THE REACTION OF ANILINE WITHDIMETHYL CARBONATE ON FAUJASITE, EMT AND BETA-ALKALINE ZEOLITES

Authors
RAO PRHP MASSIANI P BARTHOMEUF D
Citation
Prhp. Rao et al., SELECTIVITY TO N-MONO OR DIALKYLATION IN THE REACTION OF ANILINE WITHDIMETHYL CARBONATE ON FAUJASITE, EMT AND BETA-ALKALINE ZEOLITES, Catalysis letters, 31(1), 1995, pp. 115-120
Citations number
11
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
31
Issue
1
Year of publication
1995
Pages
115 - 120
Database
ISI
SICI code
1011-372X(1995)31:1<115:STNODI>2.0.ZU;2-Q
Abstract
Zeolite K-EMT is as active and selective to N-mono methylation as K-Y in the alkylation of aniline with dimethyl carbonate at 408 or 453 K. No C-alkylation occurs in the temperature range studied. At 503 K, K-X and Cs-X are about 75% selective for dialkylation to N,N-dimethylanil ine with about 97% conversion.